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KMID : 0382420000260020049
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Korean Journal of Environmental Health Society
2000 Volume.26 No. 2 p.49 ~ p.58
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Photodegradation of Phosphamidon and Profenofos
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Min Kyung-Jin
Cha Chun-Geun
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Abstract
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The present study was performed to investigate photodegradation rate constants and degradation products of phosphamidon and profenofos by the USEPA method. The two pesticides were very stable in 16 days exposure of sunlight from September 3 to 22, 1999 and humic acid had no sensitizing effect on the photolysis of each pesticide in sunlight. In the UV irradiation test, phosphamidon was rapidly degraded as increasing UV intensity. In case of UV irradiation with TiO_2 and with TiO_2 powder amount, degradation of phosphamidon was slower than UV irradiation. Photodegradation rate of profenofos was rapidly degraded as increasing UV intensity. In case of UV irradiation with TiO_2 and with TiO_2 powder amount, degradation of profenofos showed no significant difference with UV irradiation. Photodegradation rate of profenofos was slower than that of phosphamidon. In order to identify photolysis products, the extracts of degradation products were analyzed by GC/MS. The mass spectra of photolysis products of phosphamidon were at m/z 153 and 149, those of the profenofos were at m/z 208 and 240, respectively. It was suggested that the photolysis products of phosphamidon were O, O-dimethyl phosphate(DMP) and N, N-diethylchloroacetamide, those of profenofos were 4-bromo-2-chlorophenol and O-ethyl-S-propyl phosphate.
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